Fasihuddin B, Ahmad and Fraser, White and MA, Affan and Edward R. T., Tiekink and Norrihan B, Sam (2011) {4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 67 (7). m965-m965. ISSN 1600-5368
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{4-Hydroxy-N0-[(2E,3Z)-4-oxido-4- phenylbut-3-en-2-ylidene]benzohydrazidato}dimethyltin(IV).pdf Download (1MB) | Preview |
Abstract
The SnIV atom in the title compound, [Sn(CH3)2- (C17H14N2O3)], is five-coordinated within a C2N2O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is intermediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supramolecular zigzag chains propagating along the caxis direction are mediated by O—HO hydrogen bonds, and weak C—H interactions consolidate the packing.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | single-crystal X-ray study, T = 150 K, mean (C–C) = 0.005 A˚, R factor = 0.032, wR factor = 0.081, data-to-parameter ratio = 13.6, FSTS, 2011, Universiti Malaysia Sarawak, UNIMAS, universiti, university, Borneo, Malaysia, Sarawak, Kuching, Samarahan, IPTA, education, research |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology Faculties, Institutes, Centres > Faculty of Resource Science and Technology |
| Depositing User: | Karen Kornalius |
| Date Deposited: | 06 May 2015 08:36 |
| Last Modified: | 25 May 2015 07:05 |
| URI: | http://ir.unimas.my/id/eprint/7354 |
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