Kinetic Study on Heavy Metal Divalent Ions Removal using Zirconium-Based Magnetic Sorbent

Lim, Soh Fong and Lee, A. Y. W. and Chua, S. N. D and Lim, B.H. (2020) Kinetic Study on Heavy Metal Divalent Ions Removal using Zirconium-Based Magnetic Sorbent. INTERNATIONAL JOURNAL OF INTEGRATED ENGINEERING, 12 (3). pp. 225-234. ISSN 2600-7916

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Abstract

In this research, zirconium-based magnetic sorbent synthesised by chemical co-precipitation method is explored as a potential sorbent for removal of divalent metal ions from aqueous solution. The interaction characteristics between the ions and the sorbent were elucidated by instrumental analyses such as Fourier Transform InfraRed (FT-IR) Spectroscopy, Scanning Electron Microscopy (SEM), and Brunauer, Emmett, and Teller (BET) surface area analyser. Results show that the sorption rate was increased with an increase in contact time and initial metal ion concentration. Moreover, a two-stage kinetics behaviour was observed, and all the batch experiments achieved an equilibrium state within 4 hours. The evaluation of the adsorption behaviour of heavy metal divalent ions onto the magnetic sorbent was explained using two kinetic models, and it was mostly found to follow the postulate of the pseudo-second-order kinetic model. The validity of kinetic models applied in this study is also evaluated by using a normalised standard deviation.

Item Type: Article
Uncontrolled Keywords: Zirconium based magnetic, FTIR, BET.
Subjects: T Technology > TP Chemical technology
Divisions: Academic Faculties, Institutes and Centres > Faculty of Engineering
Faculties, Institutes, Centres > Faculty of Engineering
Depositing User: Gani
Date Deposited: 11 Nov 2024 07:35
Last Modified: 11 Nov 2024 07:35
URI: http://ir.unimas.my/id/eprint/46582

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