M.A., Affan and M.A., Salam and Fasihuddin Badruddin, Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta Pages 227–232, 366 (1). pp. 277-232. ISSN 0020-1693
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Abstract
The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å, c = 9.4353(2) Å.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Substituted thiosemicarbazone; Organotin(IV) complexes; Spectral analyses; Crystal structure, 2011, Universiti Malaysia Sarawak, UNIMAS, universiti, university, Borneo, Malaysia, Sarawak, Kuching, Samarahan, IPTA, education, undergraduate, research |
| Subjects: | A General Works > AC Collections. Series. Collected works |
| Divisions: | Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology Faculties, Institutes, Centres > Faculty of Resource Science and Technology |
| Depositing User: | Karen Kornalius |
| Date Deposited: | 08 May 2014 06:58 |
| Last Modified: | 29 Mar 2023 03:27 |
| URI: | http://ir.unimas.my/id/eprint/2370 |
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