Zainab, Ngaini and Dayang H., Abang Kamaluddin (2013) Synthesis of Glycosides Bearing Chalcone Derivatives via Ferrier Rearrangement. Malaysian Journal of Chemistry, 15 (1). 013-019. ISSN 1511-2292
|
PDF
Synthesis of Glycosides Bearing Chalcone (abstract).pdf Download (61kB) | Preview |
Official URL: https://www.researchgate.net/publication/291336464...
Abstract
A series of glycoside derivatives bearing chalcones moieties has been synthesized. A convenient synthetic method was performed from the reaction of 3,4,6-tri-O-acetyl-D-glucal with (E)-1-(4-alkyloxyphenyl)-3-(4-hydroxy-phenyl)prop-2-en-1-one (2a-2c) employing OC rearrangement to afford C-glycoside 4a-c over prolonged reaction times, in the presence of BF3.OEt2 as a catalyst. The compounds differ in the length of alkyl groups, CnH2n+1, where n= 7, 8 and 9.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | glycosylation, chalcones, glycosides, OC rearrangement, unimas, university, universiti, Borneo, Malaysia, Sarawak, Kuching, Samarahan, ipta, education, research, Universiti Malaysia Sarawak |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology Faculties, Institutes, Centres > Faculty of Resource Science and Technology |
| Depositing User: | Karen Kornalius |
| Date Deposited: | 15 Mar 2017 10:38 |
| Last Modified: | 15 Mar 2017 10:38 |
| URI: | http://ir.unimas.my/id/eprint/15569 |
Actions (For repository members only: login required)
 |
View Item |
