Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV)

Md. Abu, Affan and Norrihan, Sam and Fasihuddin, Ahmad and Seik Weng, N (2010) Di-n-butyl{4-hydroxy-N0-[(2-oxido-1-naphthyl-jO) methylene]benzohydrazidato-j2 O,N0}tin(IV). Acta Crystallographica Section E, 66 (5). m572-m572. ISSN 1600-5368

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Official URL: http://journals.iucr.org/e/issues/2010/05/00/bt525...


The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)2(C18H12N2O3)], O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)°]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions.

Item Type: Article
Uncontrolled Keywords: single-crystal X-ray study, T = 293 K, mean (C–C) = 0.010 A˚, disorder in main residue, R factor = 0.057, wR factor = 0.189, data-to-parameter ratio = 14.0, unimas, university, universiti, Borneo, Malaysia, Sarawak, Kuching, Samarahan, ipta, education, research, Universiti Malaysia Sarawak
Subjects: Q Science > QD Chemistry
Divisions: Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology
Depositing User: Karen Kornalius
Date Deposited: 24 Jun 2015 04:02
Last Modified: 24 Jun 2015 04:02
URI: http://ir.unimas.my/id/eprint/7962

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