1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate

Fasihuddin B, Ahmad and Md Abu, Affan and Dayang NA, Chee and Edward RT, Tiekink (2010) 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). o555 - o555. ISSN 1600-5368


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Official URL: http://journals.iucr.org/e/issues/2010/03/00/hb532...


In the title compound, C17H18N4O2S·H2O, the thio­urea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the mol­ecule as the thione S atom, a conformation that allows the formation of intra­molecular O-H...S and O-H...N hydrogen bonds. In the crystal structure, the thio­urea and water mol­ecules self-assemble into a two-dimensional array by a combination of Owater-H...Ohydrox­yl, N-H...Owater and Owater-H...S hydrogen bonds and C-H...[pi] inter­actions.

Item Type: Article
Uncontrolled Keywords: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.002 A˚, R factor = 0.038, wR factor = 0.102, data-to-parameter ratio = 16.1, unimas, university, universiti, Borneo, Malaysia, Sarawak, Kuching, Samarahan, ipta, education, research, Universiti Malaysia Sarawak
Subjects: Q Science > QD Chemistry
Divisions: Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology
Faculties, Institutes, Centres > Faculty of Resource Science and Technology
Depositing User: Karen Kornalius
Date Deposited: 05 May 2015 03:09
Last Modified: 05 May 2015 03:09
URI: http://ir.unimas.my/id/eprint/7325

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