Application of unsymmetrical bis-chalcone compounds in dye sensitized solar cell

Pan, Tze Pei and Kien, Yung Teo and Zhi-Qiang, Liu and Tsai, Jenn-Kai and Tay, Meng Guan (2019) Application of unsymmetrical bis-chalcone compounds in dye sensitized solar cell. Chemical Data Collections, 22. pp. 1-12. ISSN 2405-8300

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Abstract

A total of nine unsymmetrical bis-chalcone compounds have been synthesized and spectroscopically characterized. The unsymmetrical bis-chaclone compounds were substituted with either methoxy (OMe) or chloro (Cl) as the electron donor, and either difluoroboryl (BF2) or a ruthenium(II)-dimethylsulfoxide [Ru(II)-DMSO] complex as the electron acceptor. All these compounds were used as the dye sensitizer in dye sensitized solar cell (DSSC) by using fluorine doped tin oxide (FTO) glass coated with titanium(IV) oxide (TiO2) as the working electrode, and the indium tin oxide (ITO) glass coated with platinum as the counter electrode. The conversion efficiency of fabricated DSSCs were tested and the unsymmetrical bis-chalcone compound with OMe and BF2 substituents in the same molecule recorded the highest efficiency at 0.091%. In contrast, the unsymmetrical bis-chalcone with OMe and Ru(II)-DMSO complex has the lowest efficiency at 0.001%.

Item Type: E-Article
Uncontrolled Keywords: Push pull effectπ-conjugated systemUnsymmetrical bis-chalconeDye sensitized solar cell (DSSC)Conversion efficiencyCrystal structure, unimas, university, universiti, Borneo, Malaysia, Sarawak, Kuching, Samarahan, ipta, education, research, Universiti Malaysia Sarawak.
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology
Depositing User: Gani
Date Deposited: 25 Oct 2019 02:56
Last Modified: 23 Jun 2020 07:25
URI: http://ir.unimas.my/id/eprint/27605

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