Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT)

M.A., Salam and M.A., Affan and Fasihuddin B., Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Bohari, Yamin and Farina, Yang (2012) Synthesis, spectral characterization and crystal structure of a noveltrinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT). Journal of Organometallic Chemistry Volume 696, Issue 26, 1 January 2012, Pages 4202–4206.

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Abstract

A new trinuclear di-n-butyltin(IV) complex with pyruvic acid-N(4)-cyclohexylthiosemicarbazone (H2PACT) ligand was synthesized and characterized by elemental analyses, molar conductivity, UV–Vis, FT-IR, 1H, 119Sn NMR spectroscopy and single crystal X-ray study. Single crystal X-ray diffraction data revealed that this complex was trinuclear cyclic fashion with the pyruvic acid-N(4)-cyclohexylthiosemicarbazone ligand. In the trinuclear di-n-butyltin(IV) complex, the ligand (H2PACT) is coordinated to the central tin(IV) atoms via the carboxylato-O, the azomethine-N and the thiolato-S atoms. The trinuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of seven coordinated in distorted pentagonal bipyramidal geometry. Single crystal X-ray data indicates that the complex (1) crystallized in cubic system with space group I-43d, a = b = c = 30.3273(17) Å, α = β = γ = 90°, Z = 16, μ(MoKα) = 1.209 mm−1, F(000) = 12,144, and final R1 = 0.0390, wR2 = 0.0843 for observed reflections 4582(I > 2σ(I)).

Item Type: Article
Additional Information: Universiti Malaysia Sarawak, UNIMAS
Uncontrolled Keywords: Trinuclear di-n-butyltin(IV) complex; Pyruvic acid-N(4)-cyclohexylthiosemicarbazone; Spectral analysis; Crystal structure, 2012, Universiti Malaysia Sarawak, UNIMAS, universiti, university, Borneo, Malaysia, Sarawak, Kuching, Samarahan, IPTA, education, undergraduate, research
Subjects: A General Works > AC Collections. Series. Collected works
A General Works > AC Collections. Series. Collected works
Divisions: Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology
Depositing User: Karen Kornalius
Date Deposited: 08 May 2014 07:01
Last Modified: 17 Sep 2015 02:08
URI: http://ir.unimas.my/id/eprint/2371

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