Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]

M.A., Affan and M.A., Salam and Fasihuddin, Ahmad and Ismail, Jusoh and Mustaffa B., Shamsuddin and Hapipah M., Ali (2011) Synthesis and spectroscopiccharacterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT) : X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta, Volume 366, Issue 1, 30 January 2011, Pages 227–232.

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Abstract

The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2–4) have been synthesized and characterized by CHN analyses, molar conductivity, UV–Vis, FT-IR and 1H NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) Å, b = 9.5970(2) Å, c = 9.4353(2) Å.

Item Type: Article
Additional Information: Universiti Malaysia Sarawak, UNIMAS
Uncontrolled Keywords: Substituted thiosemicarbazone; Organotin(IV) complexes; Spectral analyses; Crystal structure, 2011, Universiti Malaysia Sarawak, UNIMAS, universiti, university, Borneo, Malaysia, Sarawak, Kuching, Samarahan, IPTA, education, undergraduate, research
Subjects: A General Works > AC Collections. Series. Collected works
A General Works > AC Collections. Series. Collected works
Divisions: Academic Faculties, Institutes and Centres > Faculty of Resource Science and Technology
Depositing User: Karen Kornalius
Date Deposited: 08 May 2014 06:58
Last Modified: 17 Sep 2015 02:06
URI: http://ir.unimas.my/id/eprint/2370

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