2-Amino-4,6-dimethylpyridinium benzoate

Mohd Razip, Asaruddin and Habibah, A Wahab and Nornisah, Mohamed and Fun, Hoong-Kun (2010) 2-Amino-4,6-dimethylpyridinium benzoate. Acta Crystallographica Section E Structure Reports Online, 66 (10). ISSN 1600-5368

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Abstract

In the title compound, C7H11N2 +·C7H5O2 −, the 2-amino-4,6-dimethyl­pyridinium cation and the benzoate anion are linked by two N—H⋯O hydrogen bonds, forming an R 2 2(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the mol­ecules are stabilized by inter­molecular N—H⋯O hydrogen bonds. A π–π inter­action, with a centroid–centroid distance of 3.661 (2) Å, is also observed.

Item Type: Article
Uncontrolled Keywords: single-crystal X-ray study; T = 296 K; mean �(C–C) = 0.003 A°, R factor = 0.044; wR factor = 0.127; data-to-parameter ratio = 11.7, unimas, university, universiti, Borneo, Malaysia, Sarawak, Kuching, Samarahan, ipta, education, research, Universiti Malaysia Sarawak
Subjects: Q Science > QD Chemistry
Divisions: Academic Faculties, Institutes and Centres > Faculty of Engineering
Depositing User: Karen Kornalius
Date Deposited: 22 Nov 2016 02:36
Last Modified: 22 Nov 2016 02:36
URI: http://ir.unimas.my/id/eprint/14382

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