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Biochar as a Carrier for Agrochemicals

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Biochar

Abstract

Biochar is a carbonaceous material with an adjustable surface structure and porosity. It can be produced by thermal decomposition from biomass under restricted oxygen conditions. Moreover, the functionalities of biochar can be enhanced through various modifications to meet the desired application, especially in agriculture. This chapter introduces the physicochemical properties of original biochar from different feedstocks and modification methods to improve biochar performances. Besides, recent studies on biochar application as a carrier for agrochemicals (fertilizers and pesticides) are discussed. Physical, chemical, and biological methods have been employed to improve the functionalities of biochar in terms of its particle sizes, surface area, pore size, adsorption, and desorption properties. Among all techniques, the chemical activation method has greater effectiveness and advantages. The recent developments of biochar as fertilizers and encapsulation material demonstrate that biochar can significantly improve crop productivity and soil properties. Moreover, the applications of biochar as a controlled release for different kinds of pesticides are mostly related to its ability in sorption and release properties.

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References

  1. Sashidhar P, Kochar M, Singh B, Gupta M, Cahill D, Adholeya A et al (2020) Biochar for delivery of agri-inputs: current status and future perspectives. Sci Total Environ 703:134892

    Article  Google Scholar 

  2. Wang Y, Peng Z, Yang Y, Li Z, Wen Y, Liu M et al (2022) Auricularia auricula biochar supported γ-FeOOH nanoarrays for electrostatic self-assembly and pH-responsive controlled release of herbicide and fertilizer. Chem Eng J 437:134984

    Article  Google Scholar 

  3. Pirsaheb M, Moradi N (2020) Sonochemical degradation of pesticides in aqueous solution: investigation on the influence of operating parameters and degradation pathway—a systematic review. RSC Adv 10(13):7396–7423

    Article  Google Scholar 

  4. Yan T, Xue J, Zhou Z, Wu Y (2021) Biochar-based fertilizer amendments improve the soil microbial community structure in a karst mountainous area. Sci Total Environ 794:148757

    Article  Google Scholar 

  5. Zhang Y, Wang J, Feng Y (2021) The effects of biochar addition on soil physicochemical properties: a review. CATENA 202:105284

    Article  Google Scholar 

  6. Khan HA, Naqvi SR, Mehran MT, Khoja AH, Khan Niazi MB, Juchelková D et al (2021) A performance evaluation study of nano-biochar as a potential slow-release nano-fertilizer from wheat straw residue for sustainable agriculture. Chemosphere 285:131382

    Article  Google Scholar 

  7. Nayak A, Bhushan B, Gupta V, Kotnala S (2021) Fabrication of microwave assisted biogenic magnetite-biochar nanocomposite: a green adsorbent from jackfruit peel for removal and recovery of nutrients in water sample. J Ind Eng Chem 100:134–148

    Article  Google Scholar 

  8. Thongsamer T, Vinitnantharat S, Pinisakul A, Werner D (2022) Chitosan impregnation of coconut husk biochar pellets improves their nutrient removal from eutrophic surface water. Sustain Environ Res 32:39

    Article  Google Scholar 

  9. Li R, Wang JJ, Zhou B, Zhang Z, Liu S, Lei S et al (2017) Simultaneous capture removal of phosphate, ammonium and organic substances by MgO impregnated biochar and its potential use in swine wastewater treatment. J Clean Prod 147:96–107

    Article  Google Scholar 

  10. Kalsoom, Khan S, Ullah R, Adil M, Waheed A, Khan KA et al (2022) Adsorption of pesticides using wood-derived biochar and granular activated carbon in a fixed-bed column system. Water 14:2937

    Google Scholar 

  11. Zhang H, Zhang R, Li W, Ling Z, Shu W, Ma J et al (2022) Agricultural waste-derived biochars from co-hydrothermal gasification of rice husk and chicken manure and their adsorption performance for dimethoate. J Hazard Mater 429:128248

    Article  Google Scholar 

  12. Li X, Luo J, Deng H, Huang P, Ge C, Yu H et al (2018) Effect of cassava waste biochar on sorption and release behavior of atrazine in soil. Sci Total Environ 644:1617–1624

    Article  Google Scholar 

  13. Sajjadi B, Chen W-Y, Egiebor NO (2019) A comprehensive review on physical activation of biochar for energy and environmental applications. Rev Chem Eng 35:735–776

    Article  Google Scholar 

  14. Qiu M, Sun K, Jin J, Gao B, Yan Y, Han L et al (2014) Properties of the plant- and manure-derived biochars and their sorption of dibutyl phthalate and phenanthrene. Sci Rep 4:5295

    Article  Google Scholar 

  15. Sumaraj, Padhye LP (2017) Influence of surface chemistry of carbon materials on their interactions with inorganic nitrogen contaminants in soil and water. Chemosphere 184:532–547

    Google Scholar 

  16. Ren L, Hao B, Fang W, Zhang D, Cheng H, Li Q et al (2022) Combination of modified biochar and polyurea microcapsules to co-encapsulate a fumigant via interface polymerization for controlled release and enhanced bioactivity. Pest Manag Sci 78:73–85

    Article  Google Scholar 

  17. Song L, Hou L, Zhang Y, Li Z, Wang W, Sun QJF (2020) Regular biochar and bacteria-inoculated biochar alter the composition of the microbial community in the soil of a Chinese fir plantation. Forests 11:951

    Article  Google Scholar 

  18. Zhang Y, Xiao X, Zhu X, Chen B (2022) Self-assembled fungus-biochar composite pellets (FBPs) for enhanced co-sorption-biodegradation towards phenanthrene. Chemosphere 286:131887

    Article  Google Scholar 

  19. Wei T, Li X, Li H, Gao H, Guo J, Li Y et al (2022) The potential effectiveness of mixed bacteria-loaded biochar/activated carbon to remediate Cd, Pb co-contaminated soil and improve the performance of pakchoi plants. J Hazard Mater 435:129006

    Article  Google Scholar 

  20. Chen S, Yang M, Ba C, Yu S, Jiang Y, Zou H et al (2018) Preparation and characterization of slow-release fertilizer encapsulated by biochar-based waterborne copolymers. Sci Total Environ 615:431–437

    Article  Google Scholar 

  21. Duhan JS, Kumar R, Kumar N, Kaur P, Nehra K, Duhan S (2017) Nanotechnology: The new perspective in precision agriculture. Biotechnol Rep 15:11–23

    Article  Google Scholar 

  22. Gwenzi W, Nyambishi TJ, Chaukura N, Mapope N (2018) Synthesis and nutrient release patterns of a biochar-based N-P–K slow-release fertilizer. Int J Environ Sci Technol 15:405–414

    Article  Google Scholar 

  23. Luo W, Qian L, Liu W, Zhang X, Wang Q, Jiang H et al (2021) A potential Mg-enriched biochar fertilizer: excellent slow-release performance and release mechanism of nutrients. Sci Total Environ 768:144454

    Article  Google Scholar 

  24. Gao M, Yang J, Liu C, Gu B, Han M, Li J et al (2021) Effects of long-term biochar and biochar-based fertilizer application on brown earth soil bacterial communities. Agric Ecosyst Environ 309:107285

    Article  Google Scholar 

  25. Chew J, Zhu L, Nielsen S, Graber E, Mitchell DRG, Horvat J et al (2020) Biochar-based fertilizer: supercharging root membrane potential and biomass yield of rice. Sci Total Environ 713:136431

    Article  Google Scholar 

  26. Sun T, Levin BDA, Guzman JJL, Enders A, Muller DA, Angenent LT et al (2017) Rapid electron transfer by the carbon matrix in natural pyrogenic carbon. Nat Commun 8:14873

    Article  Google Scholar 

  27. Husson O (2013) Redox potential (Eh) and pH as drivers of soil/plant/microorganism systems: a transdisciplinary overview pointing to integrative opportunities for agronomy. Plant Soil 362:389–417

    Article  Google Scholar 

  28. Lustosa Filho JF, Barbosa CF, Carneiro JSdS, Melo LCA (2019) Diffusion and phosphorus solubility of biochar-based fertilizer: visualization, chemical assessment and availability to plants. Soil Tillage Res 194:104298

    Google Scholar 

  29. Vakal S, Vakal V, Artyukhov A, Shkola V, Yanovska A (2023) New method for obtaining “green” encapsulated fertilizers with nanoporous structure within the concept of sustainable development. Clean Technol Environ Policy 25:963–977

    Article  Google Scholar 

  30. An X, Wu Z, Qin H, Liu X, He Y, Xu X et al (2021) Integrated co-pyrolysis and coating for the synthesis of a new coated biochar-based fertilizer with enhanced slow-release performance. J Clean Prod 283:124642

    Article  Google Scholar 

  31. Khajavi-Shojaei S, Moezzi A, Norouzi Masir M, Taghavi M (2023) Synthesis modified biochar-based slow-release nitrogen fertilizer increases nitrogen use efficiency and corn (Zea mays L.) growth. Biomass Convers Biorefin 13:593–601

    Google Scholar 

  32. Rubel RI, Wei L (2022) Biochar-based controlled release nitrogen fertilizer coated with polylactic acid. J Polym Environ 30:4406–4417

    Article  Google Scholar 

  33. Kassem I, Ablouh E-H, El Bouchtaoui FZ, Hannache H, Ghalfi H, Sehaqui H et al (2022) Cellulose nanofibers/engineered biochar hybrid materials as biodegradable coating for slow-release phosphate fertilizers. ACS Sustain Chem Eng 10:15250–15262

    Article  Google Scholar 

  34. Zhang H, Yang H, Shao J, Chen Y, Zhang S, Chen H (2023) Multifunctional carboxymethyl cellulose sodium encapsulated phosphorus-enriched biochar composites: multistage adsorption of heavy metals and controllable release of soil fertilization. Chem Eng J 453:139809

    Article  Google Scholar 

  35. Sim DHH, Tan IAW, Lim LLP, Hameed BH (2021) Encapsulated biochar-based sustained release fertilizer for precision agriculture: a review. J Clean Prod 303:127018

    Article  Google Scholar 

  36. Cara IG, Țopa D, Puiu I, Jităreanu G (2022) Biochar a promising strategy for pesticide-contaminated soils. Agriculture 12:1579

    Article  Google Scholar 

  37. Qie H, Ren M, You C, Cui X, Tan X, Ning Y et al (2023) High-efficiency control of pesticide and heavy metal combined pollution in paddy soil using biochar/g-C3N4 photoresponsive soil remediation agent. Chem Eng J 452:139579

    Article  Google Scholar 

  38. Xiang Y, Lu X, Yue J, Zhang Y, Sun X, Zhang G et al (2020) Stimuli-responsive hydrogel as carrier for controlling the release and leaching behavior of hydrophilic pesticide. Sci Total Environ 722:137811

    Article  Google Scholar 

  39. Evy Alice Abigail M (2019) Biochar-based nanocarriers: fabrication, characterization, and application as 2,4-dichlorophenoxyacetic acid nanoformulation for sustained release. 3 Biotech 9:317

    Google Scholar 

  40. de Pierri L, Novotny EH, Pellegrino Cerri CE, José de Souza A, Mattos BB, Tornisielo VL et al (2022) Accessing biochar’s porosity using a new low field NMR approach and its impacts on the retention of highly mobile herbicides. Chemosphere 287:132237

    Google Scholar 

  41. Lü J, Li J, Li Y, Chen B, Bao Z (2012) Use of rice straw biochar simultaneously as the sustained release carrier of herbicides and soil amendment for their reduced leaching. J Agric Food Chem 60:6463–6470

    Article  Google Scholar 

  42. Mei M, Bai B, Zheng D, Hu N, Wang H (2021) Novel fabrication of a yeast biochar-based photothermal-responsive platform for controlled imidacloprid release. RSC Adv 11:19395–19405

    Article  Google Scholar 

  43. Egamberdieva D, Jabbarov Z, Arora NK, Wirth S, Bellingrath-Kimura SD (2021) Biochar mitigates effects of pesticides on soil biological activities. Environ Sustain 4:335–342

    Article  Google Scholar 

  44. Ponnam V, Katari NK, Mandapati RN, Nannapaneni S, Tondepu S, Jonnalagadda SB (2020) Efficacy of biochar in removal of organic pesticide, Bentazone from watershed systems. J Environ Sci Health B 55:396–405

    Article  Google Scholar 

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Correspondence to Sumiyyah Sabar .

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Wan Yusof, W.R., Sabar, S., Md Yusof, E.N., Abdul Mubarak, N.S. (2024). Biochar as a Carrier for Agrochemicals. In: Bhawani, S.A., Bhat, A.H., Wahi, R., Ngaini, Z. (eds) Biochar. Sustainable Materials and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-97-4252-3_11

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